BIOCHAR PRODUCED FROM ANAEROBICALLY DIGESTED SUGARCANE BAGASSE: STRUCTURAL MOPHORLOGY CHARACTERIZATIONS AND APPLICATION TO REMOVE NIKEL CONTAMINANTED WAST WATER

Phan Thi Uyen Nhung; Le Thanh Huy; Chu Thi Thu Hien

Phan Thi Uyen Nhung Hung Yen University of Technology and Education
Le Thanh Huy Hung Yen University of Technology and Education
Chu Thi Thu Hien Hung Yen University of Technology and Education

Keywords: Biochar, adsorption, heavy metals

Abstract

In this study, biochar (BC) successfully produced by anaerobic heating the derived bagasse. Structural mophorlogy characteristics of the obtained materials were investigated by scanning electron microscopy methods (SEM), X-ray energy scattering spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR). SEM images show that the fabrication materials have a large specific surface, porous structure. EDS spectroscopic results show a significant change in BC's elemental composition compared to the original material. FTIR spectra indicated that the fabricated materials contain surface functional groups such as -OH, -COO, = C = O, ... Test of domestic nickel separation ability of BC material samples obtained efficiency high adsorption (90.55%) with saturated adsorption time at 35 minutes. The results of our study show that BC material made from bagasse has great potential in application of heavy metal treatment in water.

References

M. Inyang et al., “Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass,” Bioresour. Technol., 2012, vol. 110, pp. 50–56.

V. Bencko, “Nickel: a review of its occupational and environmental toxicology.,” J. Hyg. Epidemiol. Microbiol. Immunol., 1983, vol. 27, no. 2, pp. 237–47.

E. Malkoc and Y. Nuhoglu, “Investigations of nickel(II) removal from aqueous solutions using tea factory waste,” J. Hazard. Mater., 2005, vol. 127, no. 1–3, pp. 120–128.

Bộ Y Tế, “QCVN 01-1:2018/BYT về chất lượng nước sạch sử dụng cho mục đích sinh hoạt,” 2019.

Bộ Tài nguyên và Môi trường, “QCVN 08:2008/BTNMT Quy chuẩn Quốc gia về chất lượng nước mặt,” 2008.

Bộ Tài nguyên và Môi trường, “QCVN 40:2011/BTNMT về nước thải công nghiệp.” 2011.

Z. Elouear, J. Bouzid, N. Boujelben, M. Feki, F. Jamoussi, and A. Montiel, “Heavy metal removal from aqueous solutions by activated phosphate rock,” J. Hazard. Mater., 2008, vol. 156, no. 1–3, pp. 412–420.

G. Crini, “Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment,” Prog. Polym. Sci., 2005, vol. 30, no. 1, pp. 38–70.

G. Crini, “Non-conventional low-cost adsorbents for dye removal: A review,” Bioresour. Technol., 2006, vol. 97, no. 9, pp. 1061–1085.

A. Demirbas, “Heavy metal adsorption onto agro-based waste materials: A review,” J. Hazard. Mater., 2008, vol. 157, no. 2–3, pp. 220–229.

K. C. Das, M. Garcia-Perez, B. Bibens, and N. Melear, “Slow pyrolysis of poultry litter and pine woody biomass: Impact of chars and bio-oils on microbial growth,” J. Environ. Sci. Heal., 2008, vol. 43, no. 7, pp. 714–724.

S. P. Sohi, E. Krull, E. Lopez-Capel, and R. Bol, A review of biochar and its use and function in soil, 1st ed., 2010, vol. 105, no. 1. Elsevier Inc.

J. Lehmann, M. C. Rillig, J. Thies, C. A. Masiello, W. C. Hockaday, and D. Crowley, “Biochar effects on soil biota - A review,” Soil Biol. Biochem., 2011, vol. 43, no. 9, pp. 1812–1836.

B. Glaser, S. Meyer, B. Glaser, and P. Quicker, “Technical, Economical , and Climate-Related Aspects of Biochar Production Technologies: A Literature Review Technical, Economical, and Climate-Related Aspects of Biochar Production Technologies: A Literature Review,” Environ. Sci. Technol., 2015,no. SEPTEMBER 2011, pp. 9473–9483.

A. J. L. KELLI G. ROBERTS, , BRENT A. GLOY, STEPHEN JOSEPH, NORMAN R. SCOTT, “Life Cycle Assessment of Biochar Systems: Estimating the Energetic, Economic, and Climate Change Potential,” Environ. Sci. Technol., 2010, vol. 44, pp. 827–833.

H. Lu, W. Zhang, Y. Yang, X. Huang, S. Wang, and R. Qiu, “Relative distribution of Pb2+sorption mechanisms by sludge-derived biochar,” Water Res., 2012, vol. 46, no. 3, pp. 854– 862.

Y. Yao et al., “Removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tailings,” J. Hazard. Mater.,2011, vol. 190, no. 1–3, pp. 501–507.

W. Zheng, M. Guo, T. Chow, D. N. Bennett, and N. Rajagopalan, “Sorption properties of greenwaste biochar for two triazine pesticides,” J. Hazard. Mater., 2010, vol. 181, no. 1–3, pp. 121–126.

E. Agrafioti, D. Kalderis, and E. Diamadopoulos, “Arsenic and chromium removal from water using biochars derived from rice husk, organic solid wastes and sewage sludge,” J. Environ. Manage., 2014, vol. 133, pp. 309–314.

M. Inyang, B. Gao, W. Ding, P. Pullammanappallil, A. R. Zimmerman, and X. Cao, “Enhanced lead sorption by biochar derived from anaerobically digested sugarcane bagasse,” Sep. Sci. Technol., 2011, vol. 46, no. 12, pp. 1950–1956.

M. Inyang, B. Gao, P. Pullammanappallil, W. Ding, and A. R. Zimmerman, “Bioresource Technology Biochar from anaerobically digested sugarcane bagasse,” Bioresour. Technol., 2010, vol. 101, no. 22, pp. 8868–8872.

D. Mohan, H. Kumar, A. Sarswat, M. Alexandre-Franco, and C. U. Pittman, “Cadmium and lead remediation using magnetic oak wood and oak bark fast pyrolysis bio-chars,” Chem. Eng. J., 2014, vol. 236, pp. 513–528.

D. Mohan, S. Rajput, V. K. Singh, P. H. Steele, and C. U. Pittman, “Modeling and evaluation of chromium remediation from water using low cost bio-char, a green adsorbent,” J. Hazard. Mater., 2011, vol. 188, no. 1–3, pp. 319–333.